(E)-4-Hydroxy-N′-(2-hydroxy-5-iodobenzylidene)benzohydrazide methanol monosolvate
نویسندگان
چکیده
منابع مشابه
(E)-N′-(5-Chloro-2-hydroxybenzylidene)-2,4-dihydroxybenzohydrazide methanol monosolvate
In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol-ecule adopts an E conformation about the C=N bond. The compound is in the enamine-keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-mol-ecular O-H⋯O and O-H⋯N hydrogen bonding stabilizes the mol-ecular structure. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules, forming chains running along t...
متن کاملN′-(5-Bromo-2-hydroxybenzylidene)-4-nitrobenzohydrazide methanol monosolvate
In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol-ecule is nearly planar [maximum deviation = 0.110 (2) Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4 (3)°. In the benzohydrazide mol-ecule, there is an intra-molecular O-H⋯N hydrogen bond and the NH group is hydrogen bonded to the methanol solvent mol-ecule. In the crystal, inter-molecular O-H⋯...
متن کاملCrystal structure of 2-hydroxy-N-(2-hydroxyethyl)-N-{2-hydroxy-3-[(E)-N-hydroxyethanimidoyl]-5-methylbenzyl}ethanaminium acetate monohydrate
The structure of the title hydrated mol-ecular salt, C14H23N2O4 (+)·C2H3O2 (-)·H2O, was determined as part of a wider study on the use of the mol-ecule as a polydentate ligand in the synthesis of Mn(III) clusters with magnetic properties. The cation features intra-molecular O-H⋯N and N-H⋯O hydrogen-bond inter-actions. The crystal structure features a range of inter-molecular hydrogen-bonding in...
متن کاملN-(4-Fluorobenzoyl)-2-hydroxy-4-methylbenzohydrazide
In the title compound, C(15)H(13)FN(2)O(3), the aromatic rings are aligned at an angle of 10.15 (3)°. The mol-ecules are packed with π-π stacking inter-actions [mean inter-planar distances of 3.339 (2) and 3.357 (3) Å] and the crystal structure is stabilized by inter-molecular N-H⋯O and O-H⋯O hydrogen bonds. An intramolecular N-H⋯O interaction also occurs.
متن کامل(E)-4-Hydroxy-N′-(2-hydroxy-5-iodobenzylidene)benzohydrazide methanol monosolvate
In the title compound, C(14)H(11)IN(2)O(3)·CH(4)O, the dihedral angle between the benzene rings is 33.2 (3)°. The mol-ecule displays trans and anti conformations about the C=N and N-N bonds, respectively. There is an intra-molecular O-H⋯N(azomethine) hydrogen bond. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds consolidate mol-ecules into a three-dimensional architecture.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812034848